One resort who appreciates “Sunset Villas” is Atmosphere Kanifushi. There is no choosing between sunrise and sunset at this resort…because ALL the villas have been built westward facing. All four of their room types are designated “Sunset”.
In all fairness, the standard “Beach Villas”, the left most villas numbered “12” on the resort map below, are really “north” facing. In fact, all of the villas are really NNW facing if you want to be precise. North by Northwest should give you a fine view of the sunset on the western horizon in most cases. But one visitor did report to me that at certain times of the year, the sunset was really hard to see (and that would certainly be the case for the westernmost “Beach Villas”. So if you are draw to this sunset orientation of Kanifushi, you might want to veer toward the villas on the eastern most end of the island.